後藤 元信 教授・池上 知顯 教授・真下 茂 教授

極限状態の一つとして臨界温度と臨界圧力を超えた状態である超臨界流体の科学と工学への応用を研究しています。分離プロセスとして超臨界二酸化炭素や亜臨界水を使って天然物から生理活性成分を抽出・精製する研究などをしています。反応プロセスとして亜・超臨界水によるバイオマスの資源化や燃料化の研究などをしています。一方、異分野融合研究として化学と電気技術の融合プロセスを開発しています。亜・超臨界流体中でのパルスパワーによる放電プラズマやレーザーアブレーション、電気分解反応による化学反応や材料調製の新規なプロセスを研究しています。国内外の大学や企業との共同研究を積極的に推進し、基礎から実用化に至る研究を行っています。


Publications
  1. Kiathevest, K., Goto, M., Sasaki, M., Pavasant, P., Shotipruk, A., Extraction and concentration of anthraquinones from roots of Morinda citrifolia by non-ionic surfactant solution, Separation and Purification Technology, in press.
  2. Kitada, K., Machmudah, S., Sasaki, M., Goto, M., Nakashima, Y., Kumamotod, S., Hasegawad, T., Supercritical CO2 extraction of pigment components with pharmaceutical importance from Chlorella vulgaris, Journal of Chemical Technology and Biotechnology, in press.
  3. Kuwahara, Y., Morita, M., Nagami, T., Tanaka, A., Iwanaga, T., Kumamaru, K., Tsuyohi, S., Sasaki, M., Goto, M., Sato, M., Functionalization of a Polymer by Nanoparticles Immobilized in Supercritical Carbon Dioxide, Japanese Journal of Applied Physics, in press.
  4. Kuwahara, Y., Takashi, S., Minori H., Iwanaga, T., Sasaki, M., Goto, M., Nanosecond Pulsed Laser Ablation of Copper in Supercritical Carbon Dioxide, Japanese Journal of Applied Physics, in press.
  5. Omurzak, E., Mashimo, T., Iwamoto, C., Matsumoto, Y., Sulaimankulova, S. (2009) Synthesis of blue amorphous TiO2 and TinO2n-1 by the impulse plasma in liquid, J. Nanosci. NanoTechnol., in press.
  6. Thana, P., Machmudah, S., Goto, M., Sasaki, M., Pavasant, P., Shotipruk, A. (2009) Response surface methodology to supercritical carbon dioxide extraction of astaxanthin from Haematococcus pluvialis, Bioresource Technology, 99 (8) 3110-3115.
  7. Rangsriwong, P., Rangkadilok, N., Satayavivad, J., Goto, M., Shotipruk, A., Subcritical water extraction of polyphenolic compounds from Terminalia chebula Retz. Fruits, Separation and Purification Technology, in press.
  8. Saito, T., Sasaki, M., Kawanabe, H., Yoshino, Y., Goto, M., Subcritical Water Reaction Behavior of D-Glucose as a Model Compound for Biomass Using Two Different Continuous-Flow Reactor Configrations, Chemical Engineering & Technology, in press.
  9. Wahyudiono, Sasaki, M., Goto, M., Conversion of Biomass Model Compound under Hydrothermal Conditions using Batch Reactor, Fuel, in press.
  10. Ueda, T., Takahashi, K., Mitsugi, F., Ikegami, T. (2009) Preparation of single-walled carbon nanotube/TiO2 hybrid atmospheric gas sensor operated at ambient temperature., Diamond & Related Materials, 18, 493-496.
  11. Altuntasoglu, O., Unal, U., Ida, S., Goto, M., Matsumoto, Y. (2008) Characterization of self-assembled films of NiGa layered double hydroxide nanosheets and their electrochemical properties, Journal of Solid State Chemistry, 181 (12) 3257-3263.
  12. Bhuiyan, M. M. H., Katsuki, S., Ueda T., Ikegami, T. (2008) Improvement in the Sensitivity of SnO2 Thin Film Based Nox Gas Sensor by Loading with Single-Walled Carbon Nanotube Prepared by Pulsed Laser Deposition Process., Sensor Letters, 6, 1-6
  13. Fang, T., Shimoyama, Y., Abeta, T., Iwai, Y., Sasaki, M., Goto, M. (2008) Phase Equilibria for the Mixtures of Supercritical Methanol + C18 Methyl Esters and Supercritical Methanol + α-Tocopherol, Journal of Supercritical Fluids, 47 (2) 140-146.
  14. Goto, M. (2009) Chemnical recycling of plastics using sub- and supercritical fluids, Journal of Supercritical Fluids, 47 (2) 500-507.
  15. Goto, M., Adschiri, T., Han, B., Lee, Y.-W. (2008) Preface, Journal of Supercritical Fluids, 44 (3) 259.
  16. Goto, M., Sasaki, M., Kiyan, T., Fang, T., Roy, B. C., Namihira, T., Akiyama H., Hara, M. (2008) Reaction in plasma generated in supercritical carbon dioxide, Journal of Physics: Conference Series, 121 (82009) 1-8.
  17. Ihara, H., Abe, Y., Miyamoto, A., Nishihara, M., Takafuji, M., Mashimo, T., Ono, M., Okayasu S. (2008) Chemistry in Mega-gravity: Preparation of Molecular-scaled Graded Materials from Radical Copolymerization, Chemistry Letters, 37 (2) 200-201.
  18. Ihara, H., Abe, Y., Miyamoto, A., Nishihara, M., Takafuji, M., Mashimo, T., Ono, M., Okayasu, S. (2008) Chemistry in Mega-gravity: Preparation of Molecular-scaled Graded Materials from Radical Copolymerization, Chemistry Letters, 37 (2) 200-201.
  19. Kawahito, Y., Kondo, M., Machmudah, S., Sibano, K., Sasaki, M., Goto, M. (2008) Supercritical CO2 Extraction of Biological Active Compounds from Loquat Seed, Separation and Purification Technology, 61, 130-135.
  20. Kinoishita, T., Kawamura, K., mashimo, T. (2008) Molecular dynamics simulation of screw dislocation behavior under uniaxial compression: Elastoplastic transition of KCl crystal, J. Soc. Materials Sci. Jpn 57 (4), 363-367 [in Japanese].
  21. Kiyan, T., Takade, M., Namihira, T., Hara, M., Sasaki, M., Goto, M., Akiyama, H. (2008) Polarity Effect in DC Breakdown Voltage Characteristics of Pressurized Carbon Dioxide up to Supercritical Conditions, IEEE Transactions on Plasma Science, 36 (3) 821-827.
  22. Krichnavaruk, S., Shotipruk, A., Goto, M., Pavasant, P. (2008) Supercritical carbon dioxide extraction of astaxanthin from Haematococcus pluvialis with vegetable oils as co-solvent, Bioresource Technology, 99 (13) 5556-5560.
  23. Kuwahara, Y., Morita, M., Yoshimori, K., Kumamaru,K., Endoh, H., Iwanaga, T., Nagami, T., Sawada, T., Shosenji, H., Sasaki, M., Goto, M. (2008) Fabrication of Nano-Patterns Composed of Metal Nanoparticles with Photo-Nanoimprint, Japanese Journal of Applied Physics, 47, 5171-5173.
  24. Machmudah, S., Kawahito, Y., Sasaki, M., Goto, M. (2008) Process optimization and extraction rate analysis of carotenoids extraction from rosehip fruit using supercritical CO2, Journal of Supercritical Fluids, 44 (3) 308-314.
  25. Machmudah, S., Kondo, M., Sasaki, M., Goto, M., Munemasa, J., Yamagata, M. (2008) Pressure effect in supercritical CO2 extraction of plant seeds, Journal of Supercritical Fluids, 44 (3) 301-307.
  26. Mashimo, T., Ono, M., Huang, X.S., Iguchi, Y., Okayasu S., Kobayashi, K., Nakamura, E. (2008) Sedimentation of isotope atoms in monoatomic lolid Se, Euro. Phys. Lett., 81, 56002-1-4.
  27. Mashimo, T., Ono, M., Huang, X.S., Iguchi, Y., Okayasu S., Kobayashi, K., Nakamura, E. (2008) Isotope Separation by Condensed Matter Centrifuge: Sedimentation of Isotope Atoms in Se, J. Nuclear Sci. & Tech., 105-107.
  28. Ono, M., Iguchi, Y., Okayasu, S., Esaka, F., Kobayashi, K., Hao, T., Bagum, R., Osawa, T., Fujii, K., Nakamura, E., Mashimo, T. (2008) Isotope Fluctuation in Indium-Lead alloy induced by Solid Centrifugation, J. Nuclear Sci. & Tech., 108-110.
  29. Sereewatthanawut, I., Prapintip, S., Watchiraruji, K., Goto, M., Sasaki, M., Shotipruk, A. (2008) Extraction of protein and amino acids from deoiled rice bran by subcritical water hydrolysis, Bioresource Technology, 99 (3) 555-561.
  30. Saito, T., Noguchi, S., Matsumoto, T., Sasaki, M., Goto, M. (2008) The investigation of degradation reaction of various saccharides in high temperature and high pressure water, Journal of Physics: Conference Series, 121 (82010) 1-5.
  31. Sakai, N., Umeda, Y., Mitsugi, F., Ikegami, T. (2008) Characterization of zinc oxide thin films prepared by pulsed laser deposition at room temperature., Surface & Coatings Technology, 202, 5467-5470.
  32. Topal, U., Sasaki, M., Goto, M., Otles, S. (2008) Chemical CompoS.,ons and Antioxidant Properties of Essential Oils from Nine Species of Turkish Plants Obtained by Supercritical Carbon Dioxide Extraction and Steam Distillation, International Journal of Food Sciences & Nutrition, 59 (7-8) 619-634.
  33. Ueda, T., Bhuiyan, M.M.H., Norimatsu, H., Katsuki, S., Ikegami, T., Mitsugi, F. (2008) Development of carbon nanotube-based gas sensors for NOx gas detection working at low temperature, Physica E, 40, 2272-2277.
  34. Ueda, T., Katsuki, S., Heidari Abhari, N., Ikegami, T., Mitsugi, F., Nakamiya, T. (2008) Effect of laser irradiation on carbon nanotube films for NOx gas sensor., Surface & Coatings Technology, 202, 5325-5328.
  35. Ueda, T., Katsuki, S., Takahashi, K., Narges, H.A., Ikegami, T., Mitsugi, F. (2008) Fabrication and characterization of carbon nanotube based high sensitive gas sensors operable at room temperature, Diamond & Related Materials, 17, 1586-1589.
  36. Ueno, H., Tanaka, M., Hoshino, M., Sasaki, M., Goto, M. (2008) Extraction of valuable compounds from the flavedo of Citrus junos using subcritical water, Separation and Purification Technology, 62 (3) 513-516.
  37. Watchararuji, K., Goto, M., Sasaki, M., Shotipruk, A. (2008) Value-added subcritical water hydrolysate from rice bran and soybean meal, Bioresource and Biotechnology, 99 (14) 6207-6213.
  38. Wahyudiono, Sasaki, M., Goto, M. (2008) Kinetic study for liquefaction of tar in sub- and supercritical water, Polymer Degradation and Stability, 93, 1194-1204.
  39. Anekpankul, T., Goto, M., Sasaki, M., Pavasant, P., Shotipruk, A. (2007) Extraction of anti-cancer damnacanthal from roots of Morinda citrifolia by subcritical water, Separation and Purification Technology, 55 (3) 343-349.
  40. Fang, T., Goto, M., Wang, X., Ding, X., Geng, J., Sasaki, M., Hirose, T. (2007) Separation of natural tocopherols from soybean oil byproduct with supercritical carbon dioxide, Journal of Supercritical Fluids, 40 (1) 50-58.
  41. Fang, T., Wahyudiono, Al-Duri, B., Shimoyama, Y., Iwai, Y., Sasaki, M., Goto, M. (2007) Supercritical Methanol Process of Modifying Oil Byproduct for Concentrating Natural Tocopherols, Industrial and Engineering Chemistry Research, 46 (16) 5325-5332.
  42. Genta, M., Iwaya, T., Sasaki, M., Goto, M. (2007) Supercritical Methanol for Polyethylene Terephthalate Depolymerization: Observation Using Simulator, Waste Management, 27 (9) 1167-1177.
  43. Goto, M., Yamamoto, K., Sasaki, M. (2007) Reaction Mechanism and Pathway for Hydrothermal Electrolysis of Organic Compounds, Journal of Material Cycles and Waste Management, 9 (1) 40-46.
  44. Huang, X.S., Ono, M., Ueno, H., Iguchi, Y., Tomita, T., Okayasu, S., Mashimo, T. (2007) Formation of atomic-scale graded structure in Se-Te semiconductor under strong gravitational field, J. Appl. Phys., 101, 113502.
  45. Iwao, S., Abd El-Fatah, S., Furukawa, K., Seki, T., Sasaki, M., Goto, M. (2007) Recovery of palladium from spent catalyst with supercritical CO2 and chelating agent, Journal of Supercritical Fluids, 42 (2) 200-204.
  46. Kinioshita, T., Mashimo, T., Kawamura, K. (2007) Dislocation behavior in KCl crystal under uniaxial compression: Molecular dynamics simulation, J. Appl.Phys., 101, 093517-1-6.
  47. Kiyan, T., Uemura, A., Roy, B. C., Namihira, T., Hara, M., Sasaki, M., Goto, M., Akiyama, H. (2007) Negative DC Prebreakdown Phenomena and Breakdown-Voltage Characteristics of Pressurized Carbon Dioxide up to Supercritical Conditions, IEEE Transactions on Plasma Science, 35 (3) 656-662.
  48. Machmudah, S., Kawahito, Y., Sasaki, M., Goto, M. (2007) Supercritical CO2 extraction of rosehip seed oil: Fatty acids compoS.,on and process optimization, Journal of Supercritical Fluids, 41 (3) 421-428.
  49. Mashimo, T., Fan, X., Huang, X.S. (2007) Metastable Transition-Metal System Bulk Alloys prepared by MA and Shock compression", Materials Science Forum, Vols. 539-543, 1937-1942.
  50. Mashimo, T., Ono, M., Huang, X.S., Iguchi, Y., Okayasu S., Kobayashi, K., Nakamura, E. (2007) Sedimentation of isotope atoms in monoatomic liquid Se, Appl. Phys. Lett., 91, 231917.
  51. Omurzak, E., Jasnakunov, J., Mairykava, N., Abdykerimova , A., Maatkasynov, A., Sulaaimankulov, S., Matsuda, M., Nishida, M., Ihara, H., Mashimo, T. (2007) Synthesis method of nanomaterials by pulsed plasma in liquid, J. Nanosci. NanoTechnol. 7(9) 3157-3159.
  52. Pitipanapong, J., Chitprasert, S., Goto, M., Jiratchariyakul, W., Sasaki M., Shotipruk, A. (2007) New approach for extraction of charantin from Momordica charantia with pressurized liquid extraction, Separation and Purification Technology, 52 (3) 416-422.
  53. Roy, B. C., Awual, M. R., Goto, M. (2007) Effect of Inorganic Salts on Ternary Equilibrium Data of Propionic Acid-Water-Solvents Systems, Journal of Applied Sciences, 7 (7) 1053-1060.
  54. Roy, B. C., Hoshino, M., Ueno, H., Sasaki, M., Goto, M. (2007) Supercritical Carbon Dioxide Extraction of the Volatiles from the Peel of Japanese Citrus Fruits, Journal of Essential Oil Research, 19 (1) 78-84.
  55. Roy, B. C., Sasaki, M., Goto, M. (2007) Effect of temperature and pressure on the extraction yield of oil from sunflower seed with supercritical carbon dioxide, Journal of Applied Sciences, 6 (1) 71-75.
  56. Sasaki, M., Yamamoto, K., Goto, M. (2007) Reaction mechanism and pathway for hydrothermal electrolysis of organic compounds, Journal of Material Cycles and Waste Management, 9(1), 40-46.
  57. Togo, H., Zhang, Y., Kawamura, Y., Mashimo, T. (2007) Properties of Zr-based bulk metallic glass under shock compression, Materials Science and Engineering A 449-451, 264-268.Iwaya, T., Tokuno, S., Sasaki, M., Goto, M., Shibata, K. (2008) Recycling of fiber reinforced plastics using depolymerization by solvothermal reaction with catalyst, Journal of Material Science, 43 (7) 2452-2456.
  58. Wahyudiono, Kanetake, T., Sasaki, M., Goto, M. (2007) DecompoS.,on of a Lignin Model Compound under Hydrothermal Conditions, Chemical Engineering Technolgy, 30 (8) 1113-1122.
  59. Wahyudiono, Sasaki, M., Goto, M. (2007) Non-Catalytic Liquefaction of Tar with Low-Temperature Hydrothermal Treatment, Journal of Material Cycles and Waste Management, 9 (2) 173-181.
  60. Zhang, C., Lai, H., Fang, T., Goto, M. (2007) Generation of DC corona discharge in supercritical CO2, Diangong Jishu Xuebao/Transactions of China Electrotechnical Society, 22 (7) 37-41.